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High-pressure reactions can turn nonporous rocks into sponges

In deep Earth, rocks take up and release water all the time, and the effects can be wide reaching. Dehydration can cause rocks to crack and trigger earthquakes, and over geologic timescales, this water cycling can influence plate tectonics and move continents.

Schmalholz and team asked how water can move through impermeable rocks, such as those found in mantle wedges, the deep lithosphere, and the lower crust. They hypothesize that certain reactions can cause temporary porosity in these rocks. By mathematically modeling the hydration and dehydration of rock at high pressure, they derived equations to estimate how the porosity of rock changes as water cycles through it.

The research is published in the journal Geochemistry, Geophysics, Geosystems.

Previous work suggested that at very high temperatures, minerals can react with each other to form denser minerals, squeezing water out of the minerals and generating less dense, more porous rocks in the process.

As the reaction progresses, a "dehydration front" moves through the rock. On the other hand, some reactions cause rocks to act like dry sponges, soaking up surrounding water and becoming denser. The progression of this reaction is known as a hydration front.

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